Alpha Centauri is a system that consists of Alpha Centauri A and Alpha Centauri B, which are G and K class stars. Proxima Centauri is an M class star that is somewhat more distant and may or may not be a stellar companion to the other stars.
The chance of a jovian planet orbiting either ACA or ACB is rather slim as I understand, due to the fact that we would already have found a planet that massive.
As for habitable planets orbiting either star, the only hurdle would be disturbance from the other star. I've heard figures of stable orbits of only 250 million years for a planet in the habitable zone.
However if the orbits are stable enough, there is a high chance that there could be a habitable planet there that we simply haven't detected yet.
The notion of a "Goldilocks" zone or habitable zone is a fuzzy one, and highly dependant on the planet. The habitable zone for ACA would be slightly larger then that of the sun and the habitable zone for ACB slightly smaller, I'd imagine. But not by considerable amounts.