if you watch the "Align Plane" MFD, you can see which node you are launching from, for DN, launch at 042, for AN launch at 136, best ignition time is at arounf TN=300/400, depending on your ascent
as for pitch, theres usually LOADS of room for error, just get out of the thick atmosphere real fast (keep the speed down as well to preserve fuel) up to 20Km+, then just watch the orbit MFD for the values of ApA and Apt, dont let ApT get too high (thottle down) and pitch down as you approach target ApA (orbit altitude, aim for 250) to prevent that getting too high, its a bit of a balancing act, but it always works.
if you want a short guide:
First, get out of the thick atmosphere REAL quick, staying slow preserves fuel
then as you level off, watch ApA and ApT, throttle to control ApT (T for Throttle) keeping it below 500 (120 as you get very high up) (high throttle, it goes up, low throttle, it goes down), you're also better off keeping it above 40, so you dont pass it by mistake
lift your ApA by pitching up, lower it by pitching down, the balance point isnt too hard to find, just do some searching and watch the numbers
once ApA reaches the target altitude, cut the engines and coast to it, then burn PROGRADE to lower ECC to 0 (have a circular orbit)
then you're in orbit! move on to alignment, ejection burns
good lucl
-=Grover=-