Are you switching back and forth between rotation and translation? When I first attempted it myself I was all over the place.
Docking with Station V can be a pain when you first start out. What I would recommend is to try to master the stock scenario with Luna Object 1 (docking with a ShuttleA). If you haven't already got the Luna-Ob1 replacement (shiny or dark version from OrbitHanger) I recommend it, it helps to have a docking port to aim for.
The Worlds of 2001 also has another rotating station (Station III) that might be easier to dock with, a single dock per side, and no "hanger" to deal with. Good for practice.
Another point... Open any scenario and use the scenario editor and add Station V (or IV), you can set use the angular velocity button to set your bank angle for whatever you want it to be (degrees per second). If you find 1 degree per second a manageable target, then speed it up. After some practice you can line up on Station V further out, and you can recreate the movie scene with the Orion and hum "Blue Danube" to you hearts content.
Happy Orbiting, and practice, practice, practice.