The government's Nuclear and Industrial Safety Agency says 2 radioactive substances, cesium and radioactive iodine, have been detected near the Number One reactor at the Fukushima Number One nuclear power station.
The agency says this indicates that some of the metal containers of uranium fuel may have started melting. The substances are produced by fuel fission.
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The power station's operator, Tokyo Electric Power Company, began to vent air from the reactor container at 9AM on Saturday.
Under the plan, 2 valves close to the container would be opened manually, but radiation level on the second valve was found higher than expected.
The operation has been suspended because of the possibility that workers could be exposed to radiation. The utility is reportedly studying how to open the valve by replacing workers at a short interval, or using electric remote control.